n-type
Beginner
Silicon with extra free electrons, made by mixing in atoms that each have one electron to spare.
Novice
Silicon doped with donors (P, As, Sb). Electrons are the majority carriers and the Fermi level sits closer to the conduction band.
Expert
when , , and . Above roughly the material becomes degenerate and Boltzmann statistics no longer apply.
Explained in Bands, doping and the p-n junction (Transistors).